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Electrolysis of Water — Interactive Diagram

Watch an electric current split water into hydrogen and oxygen — and see why you always get twice as much hydrogen.

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TL;DR: Watch an electric current split water into hydrogen and oxygen — and see why you always get twice as much hydrogen.

Written & reviewed by the Syllab.in Academic Team (CBSE/NCERT subject experts) · Updated Jul 13, 2026

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Electrolysis of Water: Watch an electric current split water into hydrogen and oxygen — and see why you always get twice as much hydrogen.

Why it matters: Electrolysis of water is a classic decomposition reaction and a common practical/viva and exam question.

Electrolysis of Water — Step by Step

  1. Two electrodes are placed in water (with a little acid to conduct) and connected to a battery. Current begins to flow.
  2. Bubbles of gas form on both electrodes. HYDROGEN (H₂) collects at the CATHODE (–); OXYGEN (O₂) at the ANODE (+).
  3. You always collect TWICE as much hydrogen as oxygen (2:1) — because water is H₂O. Reaction: 2H₂O → 2H₂ + O₂.

Quick Notes — the Exam Crux

  • Passing electricity through water (with a little acid to help conduct) breaks it into hydrogen and oxygen gas.
  • Hydrogen (H₂) collects at the CATHODE — the negative electrode.
  • Oxygen (O₂) collects at the ANODE — the positive electrode.
  • The volume of hydrogen is DOUBLE the volume of oxygen (2 : 1), because water is H₂O — two H for every O.
  • This is a decomposition reaction: 2H₂O → 2H₂ + O₂ (energy from electricity).

Remember It (Memory Trick)

"Hydrogen doubles at the negative." At the cathode (–) you collect H₂; at the anode (+) you collect O₂ — in a 2 : 1 volume ratio.

Real-Life Example

The same idea powers hydrogen fuel: splitting water with (ideally solar) electricity gives clean hydrogen gas that can run a fuel-cell bus, releasing only water when burnt.

Test Yourself

Which gas is collected at the cathode, and how much compared to the other?

Hydrogen (H₂), at the negative cathode — and its volume is double that of oxygen.

Why is the hydrogen-to-oxygen volume ratio 2 : 1?

Because water is H₂O: each molecule has two hydrogen atoms for every one oxygen atom.

What type of reaction is electrolysis of water?

A decomposition reaction (specifically electrolytic decomposition), driven by electrical energy.

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